Thermal and mechanical properties of polypropylene, metallocene polyethylenes and their blends

  • 136 Pages
  • 1.26 MB
  • English
University of Birmingham , Birmingham
Statementby Mohammad Razavi Nouri.
The Physical Object
Pagination136, [36]p. :
ID Numbers
Open LibraryOL19087697M

Blends of a metallocene linear low density polyethylene (m-LLDPE) and polypropylene metallocene polyethylenes and their blends book copolymer (PP) have been prepared using a twin screw extruder and characterized by thermal.

A series of high density polyethylenes (HDPE) were synthesized via homogeneous polymerization with metallocene catalyst in two different reactors (glass and stainless steel).

The thermal and mechanical properties of the polyethylenes, synthesized with two types of reactor and different reaction parameters, are by: Only a few papers have been published on examination of thermal and mechanical properties of metallocene-prepared polyethylene and polypropylene blends, compared with the huge amount of works found in the literature on conventional PE and PP blends,.Cited by: 9.

N Nugay and T Tinçer, A study on blends of low and high density polyethylenes: Effect of mixing time on mechanical, thermal properties and oxidative degradation, European Polymer Journal, 30, 4, Cited by: metallocene polyethylenes and their blends book Metallocene based polypropylene has many unique properties that are unattainable with current catalyst systems.

Download Thermal and mechanical properties of polypropylene, metallocene polyethylenes and their blends PDF

Some of these attributes are narrow molecular weight and composition distribution, low extractable, low melt elasticity, and no vis-breaking required to achieve the. Additionally, these metallocene copolymers, despite their exceptionally low crystallinity, remain free flowing due to their narrow composition distribution.

These two properties combined allowing them to be used as efficient impact modifiers for rigid matrices such as polypropylene [1], [2], [3].Cited by: 6. Dynamic measurements in a plate−plate system and steady state flow experiments in a capillary die are presented for conventional high-density polyethylenes (HDPEs) and a new type of polyolefin.

The latter, the so-called metallocene-catalyzed HDPEs, are characterized by their low polydispersity and the total absence of branching.

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The metallocene-catalyzed materials show a different. Thermal and dynamic mechanical analysis on metallocene ULDPE/PP blends to optimize impact properties Article in Thermochimica Acta August. Dipak Rana, Kyucheol Cho, Taewoo Woo, Byung H.

Lee and Soonja Choe, Blends of ethylene 1‐octene copolymer synthesized by Ziegler–Natta and metallocene catalysts. Thermal and mechanical properties, Journal of Applied Polymer Science, 74, 5, (), (). The mechanical properties of prepared PP-Vectra A blends were compared in respect of their Young's moduli, ultimate tensile strength (UTS), percent elongation at break, toughness, hardness and.

Yousfi M, Livi S, Dumas A et al () Compatibilization of polypropylene/polyamide 6 blends using new synthetic nanosized talc fillers: Morphology, thermal, and mechanical properties. J Appl Polym Sci (1–12).Cited by: 1. Good mechanical properties were reported for PP or PE blends with chlorosulfonated polyethylene, wt% CSR, and filled with a large amount of CaSO 4.

Shikata, K. Okamura, S. Nakamura, Japanese Patent13 Decto Tokuyama Soda Co. LLDPE was blended with atactic polypropylene, –5 wt% aPP. The changes in molecular architecture for metallocene linear low-density polyethylenes (m-LLDPE) have a dramatic impact on their physical properties.

The physical properties of metallocene resins that are affected include the frictional, rheological, and melting behavior. These properties affect extrusion performance and screw design. The thermal and rheological properties of two types of metallocene‐catalyzed linear low‐density PEs (mLLDPEs) and two LDPEs, as well as their blends, were studied using differential scanning calorimeter (DSC) measurements and by: Blends of metallocene linear low-density polyethylene (m-LLDPE) and polypropylene random copolymer (PP) with three different weight ratios of 10/90.

Purchase Metallocene Catalyzed Polymers - 1st Edition. Print Book & E-Book. ISBNIn this paper the effect of various polyethylenes (PE) as well as Ziegler-Natta polypropylene (ZNPP) on thermal behaviour of metallocene polypropylene (mPP) in the oriented and un-oriented polymer blend fibres is presented.

The DSC 7 apparatus (Perkin Elmer) for measurement of thermal properties of these fibres was used. The oriented and un Cited by: 1. In this paper the effect of various polyethylenes (PE) as well as Ziegler-Natta polypropylene (ZNPP) on thermal behaviour of metallocene polypropylene (mPP) in the oriented and un- oriented.

Besides, the mechanical properties including strength, elongation, modulus of elasticity, yield of strength, Izod impact strength, hardness, thermal properties (differential scanning calorimetry and melt flow index), and morphological properties (scanning electron microscopy) of polymer blends and their fibers were : Dilara Kocak, Mehmet Akalin, Nigar Merdan.

Melt blending of linear low density polyethylene (LLDPE) and polylactide (PLLA) was performed in an extrusion mixer with post extrusion blown film attachment with and without compatibilizer-grafted low density polyethylene maleic anhydride.

The blend compositions were optimized for tensile properties as per ASTM D Based on this, LLDPE 80 (80 wt% LLDPE & 20 wt% PLLA) and M Cited by: As a result of the very high co-monomer content and homogeneous short branch distributions made possible by the metallocene catalyst, superior low temperature mechanical properties are possible.

We have studied a series of these polymers varying in density from to kg 1 −1 using dynamic mechanical by: Metallocene Catalyzed Polymers by George M. Benedikt,available at Book Depository with free delivery worldwide.

Polypropylene is a tough, rigid and crystalline thermoplastic produced from propene (or propylene) monomer. It is a linear hydrocarbon resin. The chemical formula of polypropylene is (C3H6)n. PP is among the cheapest plastics available today. Molecular Structure of Polypropylene. PP belongs to polyolefin family of polymers and is one of the top.

Effect of Metallocene Polyethylene on Heat Sealing Properties of Low Density Polyethylene Blends 53 Juan D. Sierra, Mar˝a del Pilar Noriega and Tim A.

Osswald Extrusion Operation Window for Filled Metallocene Polyethylenes 61 Mar˝a del Pilar Noriega and Tim A. Osswald, Omar A. Estrada.

Phase separation in polypropylene and metallocene polyethylene blends. Rheological and thermal properties of ethylene-styrene copolymers. Electrical conductivity and rheological behavior of multiphase polymer composites containing conducting carbon black. In this study, the synthesis of polyethylenes has been carried out with titanium-magnesium supported Ziegler-Natta catalysts in laboratory-scale reactors.

A correlation of different polymerization conditions with thermal and mechanical properties of polyethylenes has been established.

Description Thermal and mechanical properties of polypropylene, metallocene polyethylenes and their blends PDF

It is seen that there is lowering of molecular weight (Mw), polymer yield, and catalyst activity at high Cited by: 9.

Rheological aspects of blends of metallocene-catalyzed atactic polypropylenes with bitumen. Polymer Engineering & Science44, DOI: /pen Wen-Jun Wang, Zhibin Ye, Hong Fan, Bo-Geng Li, Shiping Zhu. Dynamic mechanical and rheological properties of metallocene-catalyzed long-chain-branched ethylene/propylene by: The combination of high-density polyethylene (HDPE), low-density polyethylene (LDPE) and polypropylene (PP) is frequently found in polymer waste streams.

Because of their similar density, they cannot be easily separated from each other in the recycling stream. Blending of PP/ polyethylenes (PEs) in different ratios possibly eliminate the sorting process used in the regular recycling : Chuanchom Aumnate, Natalie Rudolph, Majid Sarmadi.

Şirin, K, Balcan, M. Mechanical properties and thermal analysis of low-density polyethylene + polypropylene blends with dialkyl peroxide. Polym Adv Technol ; Cited by: 6. Processing Trends of Metallocene Linear Low Density Polyethylenes and Their Influence on Single Screw Design Influence of mPE Grades on the Dynamic Properties of PP/mPE-Blends A Single-Site Catalyzed Polyolefin for Fresh-Cut Produce Packaging: A Comparison between Monoextruded Blends and Co-Extruded Film.

The same rules of density apply to both metallocene and conventional polyethylenes. The lower the density, the softer and lower melting point; the higher the density, the stiffer and higher melting point. By blending different grades of metallocene resins with other LDPE resins, we tailor the film properties for precise performance requirements.Mohammad Razavi Nouri has written: 'The Thermal and mechanical properties of polypropylene, metallocene polyethylenes and their blends' Asked in Math and Arithmetic.

generation metallocene polyethylene resins combine these properties with increased stiffness and excellent processability. Our metallocene polyethylene can be processed at high output rates with low extrusion pressures and good gauge control in comparison with conventional LLDPE and first generation metallocene polyethylene film Size: KB.